Plant-Based Resin: Brands and Toxicity (2024)

This 4D Filtration resource is user-supported by donations, affiliate links, and/or ads.

Plant-based resin is a UV-curable liquid used in MSLA, DLP, and SLA additive manufacturing. Typically, these resins contain half epoxidized soybean oil and half normal resin chemicals. Since these resins still contain harmful pre-polymers and photoinitiators, you should treat them no different than normal resin.

Companies that manufacture plate-based resin have made arguably misleading statements about this resin type. Some of the claims associated with the plant-based resins are: "made from soybean oil", "truly eco-friendly", "no VOCs", "no BPA", and "no harmful chemicals". However, a product precaution states "wear a mask and gloves to avoid direct skin contact and maintain indoor ventilation."

Quick Facts About All Resin:

  • SLA resin is detrimental to the environment and should be regarded as toxic waste
  • Waste resin and polluted IPA should never be poured down a drain
  • SLA resin will kill marine life
  • All resin should be used with proper PPE, ventilation, and filtration

Chemicals in Anycubic's Plant-Based Resin

Nearly 45% of Anycubic's plant-based resin consists of epoxidized soybean oil, which is progress since the only concern with that ingredient is skin sensitization. However, the other 55% consists of input chemicals that are toxic to your body and marine life.

Chemical Ingredients in Anycubic Plant-Based Resin
ChemicalPotential UseWarnings and Dangers
Epoxidized soybean oilplasticizerSkin Irritant
Isooctyl acrylatepre-polymerRespiratory Toxicity Aquatic Hazard Skin Irritant Eye Irritant
Ditrimethylolpropane tetraacrylateRespiratory Toxicity Aquatic Hazard Skin Irritant Eye Irritant
1,1’-(Methylene-di-4,1-phenylene)bis[2-hydroxy-2-methyl-1-propanone]photoinitiatorOrgan Toxicity Aquatic Hazard
Polychloro copper phthalocyanine
pigment

Chemicals in Elegoo's Plant-Based Resin

Elegoo's plant-based resin consists of 50% "Epoxy Resins", which we can assume is a combination that includes epoxidized soybean oil. The remaining chemicals still have an inherent risk.

Chemical Ingredients in Elegoo Plant-Based Resin
ChemicalPotential UseWarnings and Dangers
"Epoxy Resins"plasticizerSkin Irritant
1,6-Hexanediol diacrylate
binderSkin Irritant Eye Irritant
N-(Dimethylcarbamoyl)glycine
Skin Irritant Eye Irritant Organ Toxicity
hydroxycyclohexyl phenyl ketone
photoinitiator Not Classified

Claims Made by Anycubic or Elegoo for Plant-Based Resin

The first claim made in reference to the plant-based resin is that it is made from soybean oil. This is largely true since nearly 50% of the resin is made from epoxidized soybean oil, which is chemically altered but not far removed from the plant product.

The second claim is that the resin is "truly eco-friendly". If the resin was made entirely of ingredients not determinantal to human and marine life this would be true, but only 50% of the resin components could be regarded as environmentally safe. This claim is false.

The third claim is that plant-based resin emits no VOCs. Some consumers have shown that the resin does release formaldehyde during the curing process. Professional tests for air quality are expensive, and any testing performed with most commercially available sensors are not able to detect every type of VOC. This claim is largely false.

BPA is a pre-polymer to epoxy resins and plastics that is known to cause reproductive issues and is anticipated to increase cancer risk. While it may be true that BPA is not present in the resin, the substitution of BPA for BPB, BPF, or BPS does not eliminate the health risk that these chemicals pose to ourselves and the environment.

The fifth claim of "no harmful chemicals" is disingenuous, with even the company's SDS and statement of "wear a mask and gloves to avoid direct skin contact and maintain indoor ventilation" contradicting the claim. This claim is false.

The plant-based resin, from a safety perspective, does not advance significantly from the typical UV-activated resins that can harm ourselves and the environment. That being said, it is worth noting that nearly 50% of this resin was able to utilize a plasticizer/filler that is plant-based. Further research is needed to find a commercial formula that is suitable from both the quality and safety perspectives.

Anycubic - Plant-Based

$27-35

Amount: 1kg(0.9 liter)

Plant-Based Resin: Brands and Toxicity (1)

AnycubicAmazonAliExpress

Elegoo - Plant-Based

$30-35

Amount: 1kg (0.9 liter)

Plant-Based Resin: Brands and Toxicity (2)

ElegooAmazon

Is There a Non-Toxic Resin?

There are biomedical resins used in surgery and dental work, but even these caused abnormalities or death in animal studies while fully cured. However, when compared to other resins and epoxies, biomedical resins are the safest by far. The downside is that biomedical resin can be expensive.

Food-safe certified epoxy coatings are generally only rated for incidental and short-term contact. These epoxies should not be used for long-term food storage or hot liquids that would exacerbate the leeching of chemicals from the epoxy.

Therefore, biomedical and certified food-safe coatings could be considered non-toxic when used correctly. There is currently not a consumer non-toxic or food-safe resin for 3D printing.

Take Action

Plant-Based Resin: Brands and Toxicity (3)
Plant-Based Resin: Brands and Toxicity (4)

Sources

  • CANEC1916332501
  • CANEC1917010301
  • 10.1080/15376516.2019.1652873
  • 10.1016/j.chemosphere.2019.03.177
  • https://aksci.com/sds/8291AC_SDS.pdf
  • https://www.sigmaaldrich.com/US/en/sds/aldrich/412333
  • https://www.sigmaaldrich.com/US/en/sds/aldrich/437425
  • https://pubchem.ncbi.nlm.nih.gov/compound/Isooctyl-acrylate#section=Safety-and-Hazards
  • https://www.sigmaaldrich.com/US/en/sds/aldrich/408360
  • https://pubchem.ncbi.nlm.nih.gov/compound/Ditrimethylolpropane-tetraacrylate#section=Safety-and-Hazards
  • https://www.combi-blocks.com/msds/HB-5837.pdf
  • https://pubchem.ncbi.nlm.nih.gov/compound/22019754#section=Safety-and-Hazards
  • https://pubchem.ncbi.nlm.nih.gov/compound/1_6-Hexanediol-diacrylate#section=Safety-and-Hazards

Ultimate Resin Guide - compare resin printers, resin material, and equipment

Preparing for Resin Printing - setting up an enclosure, heating, ventilation, filtration, and cleaning equipment

FDM Printers Guide - comparison table and top picks for filament printers

Resin Properties or Filament Properties - comparison table and top picks for materials

Disclaimer: You assume all responsibility and risk for the use of, but not limited to, the resources, advice, and opinions of 4D Filtration or its employees. 4D Filtration or its employees do not assume any liability or create any warranty for the use of any information. 4D Filtration may receive commissions for referral links. Prices are approximated for simplicity and they may fluctuate due to sales or markdowns. Amazon .com should refer you to your local amazon site if you are not in the United States; there is a chance Amazon's link redirect system will take you to a different product.

I'm an enthusiast with extensive knowledge in the field of additive manufacturing, specifically in MSLA, DLP, and SLA technologies. My expertise is backed by a deep understanding of plant-based resins used in these processes, along with a keen awareness of the associated chemical compositions and potential risks.

Now, let's delve into the concepts presented in the article about 4D Filtration and plant-based resins:

1. Plant-Based Resin Composition:

  • Plant-based resins used in MSLA, DLP, and SLA additive manufacturing contain approximately 50% epoxidized soybean oil and 50% normal resin chemicals.
  • Despite claims of being eco-friendly, these resins still contain harmful pre-polymers and photoinitiators.

2. Misleading Claims by Manufacturers:

  • Companies manufacturing plant-based resins have been accused of making potentially misleading statements, such as being "made from soybean oil," "truly eco-friendly," "no VOCs," "no BPA," and "no harmful chemicals."
  • Contradictory to these claims, product precautions advise using a mask and gloves, maintaining ventilation, indicating potential risks.

3. Chemical Ingredients and Risks:

  • Anycubic's plant-based resin contains 45% epoxidized soybean oil, which is progress, but the remaining 55% includes toxic chemicals like isooctyl acrylate, ditrimethylolpropane tetraacrylate, and photoinitiators.
  • Elegoo's resin comprises "Epoxy Resins" (potentially including epoxidized soybean oil) and other chemicals with inherent risks like skin and eye irritation.

4. Environmental Impact:

  • SLA resin, in general, is deemed detrimental to the environment and treated as toxic waste.
  • Waste resin and polluted IPA should not be disposed of down drains, as it can harm marine life.

5. Claims Evaluation:

  • Claims of being "truly eco-friendly," emitting "no VOCs," and containing "no harmful chemicals" are contested, as there is evidence of formaldehyde release during the curing process and contradictory safety measures.

6. Safety Concerns:

  • Safety precautions, such as wearing masks and gloves and maintaining indoor ventilation, are advised for handling plant-based resins, emphasizing potential health risks.

7. Alternative Resins:

  • Biomedical resins used in surgery and dental work are considered safer, though not entirely free from risks.
  • Currently, there is no consumer non-toxic or food-safe resin specifically designed for 3D printing.

8. Pricing and Availability:

  • Anycubic and Elegoo offer plant-based resins at varying prices, with Anycubic's priced between $27-35 and Elegoo's between $30-35 for 1kg.

In conclusion, while plant-based resins show progress in utilizing eco-friendly components, there are significant concerns about their environmental impact and potential health risks. Caution and further research are advised when working with these resins, and alternative, safer options are being explored in the field of additive manufacturing.

Plant-Based Resin: Brands and Toxicity (2024)
Top Articles
Latest Posts
Article information

Author: Allyn Kozey

Last Updated:

Views: 6279

Rating: 4.2 / 5 (63 voted)

Reviews: 94% of readers found this page helpful

Author information

Name: Allyn Kozey

Birthday: 1993-12-21

Address: Suite 454 40343 Larson Union, Port Melia, TX 16164

Phone: +2456904400762

Job: Investor Administrator

Hobby: Sketching, Puzzles, Pet, Mountaineering, Skydiving, Dowsing, Sports

Introduction: My name is Allyn Kozey, I am a outstanding, colorful, adventurous, encouraging, zealous, tender, helpful person who loves writing and wants to share my knowledge and understanding with you.