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Solution The salts are classified in the following ways:– (1) Normal Salts The salts which are obtained by complete replacement of the ionizable hydrogen ions or hydroxyl ion by a metallic ion of the base are called normal salts. Example: Hydrochloric acid(HCl) reacts with Sodium hydroxide(NaOH) to form sodium chloride(NaCl) and water(H2O). HCl(aq)+NaOH(aq)→NaCl(s)+H2O(l) (2) Acidic Salts The salts which are obtained by the partial replacement of ionizable hydrogen atoms of a polybasic acid by a metal ion of the base are called acidic salts. Example: Sulphuric acid(H2SO4) reacts with Sodium hydroxide(NaOH) to form Sodium hydrogen sulphate(NaHSO4) and water. H2SO4(aq)+NaOH(aq)→NaHSO4(s)+H2O(l) (3) Basic Salt The salt which is formed by partial replacement of hydroxyl (–OH) groups of a poly acidic base by an acid radical is called basic salts. Example: Lead hydroxide(Pb(OH)2) reacts with hydrochloric acid(HCl) to Lead oxychloride and water. Pb(OH)2(aq)+HCl(aq)→Pb(OH)Cl(s)+H2O(l) Lead hydroxide Lead oxychloride (4) Double salt The salt which is obtained by the crystallization of two simple salts or from a mixture of their saturated salt solutions is known as double salts. Example: Potash alum K2SO4+Al2(SO4)3+24H2O→K2SO4.Al2(SO4)3.24H2O Potash alum (Double salt) (5) Mixed Salt The salts containing more than one cation or anion other than H+ or OH– ions are called mixed salts. Example: Bleaching powder(CaOCl2) contains two anions Cl− and OCl−)
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